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Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy

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https://figshare.com/articles/dataset/Branch_Selective_Iridium_Catalyzed_Hydroarylation_of_Monosubstituted_Alkenes_via_a_Cooperative_Destabilization_Strategy/2036931
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资源简介:
Highly branch-selective, carbonyl-directed hydro­aryl­ations of mono­substituted alkenes are described. The chemistry relies upon a cationic Ir­(I) catalyst modified with an electron deficient, wide bite angle bis­phosphine ligand. This work provides a regio­isomeric alternative to the Murai hydro­aryl­ation protocol.
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2015-12-17
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