De Novo Synthesis of Aceric Acid and an Aceric Acid Building Block
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https://figshare.com/articles/dataset/De_Novo_Synthesis_of_Aceric_Acid_and_an_Aceric_Acid_Building_Block/3053869
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资源简介：
The de novo synthesis of an aceric acid thioglycoside
building block and the total synthesis of the plant carbohydrate aceric acid are described via a highly convergent
strategy. Aldol reaction of acetaldehyde and a protected
tartaric acid derivative provided the open chain carbohydrate.
Subsequent acid treatment yielded the aceric acid thioglycoside in 35% total yield over five steps. Oxidative cleavage
of the thioketal in the open chain carbohydrate and basic
hydrolysis of the methyl ester furnished fully deprotected
aceric acid in 31% yield over six steps.
创建时间：
2016-02-29
