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K(NpO2)3(H2O)Cl4: A Channel Structure Assembled by Two- and Three-Center Cation–Cation Interactions of Neptunyl Cations

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/K_NpO_sub_2_sub_sub_3_sub_H_sub_2_sub_O_Cl_sub_4_sub_A_Channel_Structure_Assembled_by_Two_and_Three_Center_Cation_Cation_Interactions_of_Neptunyl_Cations/2644720
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A Np(V) compound containing three-center cation–cation interations, K(NpO2)3(H2O)Cl4, has been prepared by reacting Np(V) with KCl in molten boric acid. This compound forms a three-dimensional channel structure that is constructed from both two- and three-center cation–cation interactions. Three new bonding modes for cation–cation interactions are added to the summary of all known Np(V) compounds.
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2016-02-23
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