A Calcium Coordination Framework Having Permanent Porosity and High CO2/N2 Selectivity
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https://figshare.com/articles/dataset/A_Calcium_Coordination_Framework_Having_Permanent_Porosity_and_High_CO_sub_2_sub_N_sub_2_sub_Selectivity/2526595
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A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt % CO2 uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of ∼31 kJ/mol and a CO2/N2 selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.
创建时间：
2016-02-21
