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Synthesis and Crystal Structure of Ethyl Zinc Chloride

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https://figshare.com/articles/dataset/Synthesis_and_Crystal_Structure_of_Ethyl_Zinc_Chloride/3233893
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Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn3Cl3 rings, which differ from the well-known structure of [EtZnI]∞ in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.
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2006-03-13
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