Slow Magnetic Relaxation in Octahedral Cobalt(II) Field-Induced Single-Ion Magnet with Positive Axial and Large Rhombic Anisotropy
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https://figshare.com/articles/dataset/Slow_Magnetic_Relaxation_in_Octahedral_Cobalt_II_Field_Induced_Single_Ion_Magnet_with_Positive_Axial_and_Large_Rhombic_Anisotropy/2282533
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资源简介：
Pseudooctahedral
mononuclear cobat(II) complex [Co(abpt)2(tcm)2] (1), where abpt = 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole
and tcm = tricyanomethanide anion, shows field-induced slow relaxation
of magnetization with U = 86.2 K and large axial
and rhombic single-ion zero-field-splitting parameters, D = +48(2) cm–1 and E/D = 0.27(2) (D = +53.7 cm–1 and E/D = 0.29 from ab initio CASSCF/NEVPT2
calculations), thus presenting a new example of a field-induced single-ion
magnet with transversal magnetic anisotropy.
创建时间：
2016-02-17
