β-Diiminate Platinum Complexes for Alkane Dehydrogenation
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https://figshare.com/articles/dataset/_Diiminate_Platinum_Complexes_for_Alkane_Dehydrogenation/3356119
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New five-coordinate Pt(IV) complexes [{(o-R2-p-R‘-C6H2)NC(R‘ ‘)}2CH]PtMe3 (R, R‘, R‘ ‘ = alkyl or H) are reported. The complex with R = Me, R‘ = tBu, R‘ ‘ = Me generates unsaturated Pt(II) species capable of alkane C−H bond activation and stoichiometric dehydrogenation.
创建时间:
2016-05-07



