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β-Diiminate Platinum Complexes for Alkane Dehydrogenation

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NIAID Data Ecosystem2026-03-06 收录
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New five-coordinate Pt(IV) complexes [{(o-R2-p-R‘-C6H2)NC(R‘ ‘)}2CH]PtMe3 (R, R‘, R‘ ‘ = alkyl or H) are reported. The complex with R = Me, R‘ = tBu, R‘ ‘ = Me generates unsaturated Pt(II) species capable of alkane C−H bond activation and stoichiometric dehydrogenation.

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2016-05-07
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