The rate of elementary reactions usually rises with increasing temperature. In rare cases, however, a slowdown is observed instead. One example of this is hydrogen-atom abstraction from the iron(II)-
The dicobaltocenium ion [Cc2NH]2+ [H–1]2+ was obtained via nucleophilic substitution of the nitro group of [Cc–NO2]+ by amino cobaltocenium [Cc–NH2]+ (Cc = Co(η5-C5H4)(η5-C5H5)). [H–1]2+ is moderate
Bovine heart cytochrome c oxidase is an electron-current driven proton pump. To investigate the mechanism by which this pump operates it is important to study individual electron- and proton-transfer
Separated concerted proton–electron transfer (sCPET) reactions of two series of phenols with pendent substituted pyridyl moieties are described. The pyridine is either attached directly to the phenol
