Chromium–Chromium Interaction in a Binuclear Mixed-Valent CrI–CrII Complex
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Chromium_Chromium_Interaction_in_a_Binuclear_Mixed_Valent_Cr_sup_I_sup_Cr_sup_II_sup_Complex/2240143
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资源简介：
A mixed-valent CrI–CrII binuclear complex, {κ1,κ2,κ3-N,P,P-cyclo[(Ph)PCH2N(CH2Ph)CH2]}2(CrCl2)[Cr(μ-Cl)(AlClMe2)]·4toluene (1), of a P2N2 cyclic ligand was obtained upon treatment of the chromium precursor with alkylaluminum. Complex 1 was accessible from either its trivalent or divalent precursors, and density functional theory calculations revealed the presence of only σ- and π-orbital interactions in the Cr–Cr bond.
创建时间：
2016-02-16
