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Co−C Bond Homolysis: Reactivity Difference between Alkyl- and Benzylcobaloximes

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Figshare2007-05-21 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Co_C_Bond_Homolysis_Reactivity_Difference_between_Alkyl-_and_Benzylcobaloximes/12080829
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The Co−C bond is activated toward homolysis due to the interactions between axial and equatorial dioxime ligands. Benzylcobaloxime gives an oxygen-inserted product, whereas the alkyl derivative forms air-stable cobalt(II). The stabilization of the axial R group due to the interaction between axial and equatorial ligands causes the reactivity difference.
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2007-05-21
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