In Situ Generation of NiO Nanoparticles in a Magnetic Metal–Organic Framework Exhibiting Three-Dimensional Magnetic Ordering
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https://figshare.com/articles/dataset/In_Situ_Generation_of_NiO_Nanoparticles_in_a_Magnetic_Metal_Organic_Framework_Exhibiting_Three-Dimensional_Magnetic_Ordering/4272311
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资源简介:
NiO nanoparticles
were in situ formed in a new metal–organic framework (MOF),
[Ni3(pyip)2(HCOO)2(H2O)2]n [1; H2pyip = 5-(pyridine-4-yl)isophthalic acid], which was characterized
by Fourier transform infrared spectroscopy, elemental analysis, thermogravimetric
analysis, transmission electron microscopy, and powder and single-crystal
X-ray diffraction. The MOF 1 shows a 3,6-connected three-dimensional
rtl topology network with a topological symbol of (4.62)2(42.610.83). Magnetic
property studies showed that the combination of NiO nanoparticles
within the magnetic MOF leads to the occurrence of long-range magnetic
ordering below a critical temperature of 18 K.
创建时间:
2016-11-30



