Hydrogallation of Alkynes: Syntheses of Carbon−Gallium Cages Possessing Heteroadamantane Structures
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https://figshare.com/articles/dataset/Hydrogallation_of_Alkynes_Syntheses_of_Carbon_Gallium_Cages_Possessing_Heteroadamantane_Structures/3771378
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资源简介：
Treatment of the alkynes R‘C⋮CH (R‘ = Me, n-Pr) with dialkylgallium hydrides, R2GaH
(R = Me, Et), yielded symmetrical carbon−gallium cage compounds with release of
dihydrogen and subsequent addition of Ga−H to the C⋮C triple bonds. Heteroadamantane-type compounds (GaR)6(CR‘)4 were formed in which the positions of the methylene bridges
of the carbon skeleton in adamantane were occupied by coordinatively unsaturated,
tricoordinate gallium atoms.
创建时间：
2016-08-26
