Phosph(on/in)ate-Bridged Vanadium(IV) Dimers: Synthesis and Characterization
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Phosph_on_in_ate_Bridged_Vanadium_IV_Dimers_Synthesis_and_Characterization/2494837
下载链接
链接失效反馈官方服务：
资源简介：
A series of dinuclear organophosphorus-bridged complexes
of the
general formula {(LVO(μ-O2PRR′)}2 [L = η5-cyclopentadienyltris(diethylphosphito-κ1P) cobaltate(III)] has been synthesized as
a structural model for the industrially used vanadium phosphate oxidation
catalysts. These dimeric species contain two vanadium centers in a
VO6 environment bridged by O–P–O units. These
complexes have been characterized via spectral and magnetic analyses.
Structural parameters have been analyzed through X-ray diffraction.
The dimers generally exist in either a cis/cis-anti
or retracted chair conformation in the solid state. The syntheses,
structural, spectral, and magnetic data are presented and discussed
here.
创建时间：
2012-08-20
