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Coordination Symmetry-Dependent Structure Restoration Function of One-Dimensional MOFs by Molecular Respiration

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https://figshare.com/articles/dataset/Coordination_Symmetry_Dependent_Structure_Restoration_Function_of_One_Dimensional_MOFs_by_Molecular_Respiration/3037267
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One-dimensional metal−organic compounds with cis, trans symmetry-controlled counter anions were synthesized (cis compound {[Cu(azpy)(H2O)2(OTs)2]·2H2O·(acetone)} (1) and trans compound {[Cu(H2O)4Cu(azpy)2(OTs)2(H2O)2]·2(OTs)·2H2O·2EtOH} (2)). Only 2, having trans conformation, exhibited a complete structure-restoration effect with a mechanism involving layering of molecular “bricks” of water and solvent molecules.
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2006-12-28
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