Aliphatic and Aromatic Intramolecular C−H Activation on Cp*Ir(NHC) Complexes
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https://figshare.com/articles/dataset/Aliphatic_and_Aromatic_Intramolecular_C_H_Activation_on_Cp_Ir_NHC_Complexes/3068086
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资源简介：
Facile intramolecular aliphatic and aromatic C−H activations have been observed for a series of
complexes based on the “Cp*Ir(NHC)” fragment (NHC = 1-diphenylmethyl-3-methylimidazol-2-ylidene,
1-tert-butyl-3-methylimidazol-2-ylidene, 1-benzyl-3-tert-butylimidazol-2-ylidene, and 1-benzyl-3-isopropylimidazol-2-ylidene). We have performed a series of experiments for elucidating the factors that
determine the aromatic or aliphatic C−H activations that occur. In the cases where both aliphatic and
aromatic C−H activations are possible, steric factors govern the selectivity of the reaction.
创建时间：
2016-03-01
