Knölker-Type Iron Complexes Bearing an N‑Heterocyclic Carbene Ligand: Synthesis, Characterization, and Catalytic Dehydration of Primary Amides
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https://figshare.com/articles/dataset/Kno_lker_Type_Iron_Complexes_Bearing_an_N_Heterocyclic_Carbene_Ligand_Synthesis_Characterization_and_Catalytic_Dehydration_of_Primary_Amides/2127763
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资源简介：
A family of iron Knölker-type
complexes bearing an N-heterocyclic
carbene (NHC) ligand has been synthesized from the corresponding tricarbonyl(η4-cyclopentadienone)iron complex by reaction with the in situ
generated NHC ligand, under UV irradiation (350 nm) at room temperature.
The six complexes, obtained in good yields (64–84%) after purification
on column chromatography, were fully characterized, including X-ray
diffraction and electrochemical studies. The activity of these complexes
in catalysis has been demonstrated for the dehydration of primary
benzamides into benzonitriles under hydrosilylation conditions using
inexpensive polymethylhydrosiloxane (PMHS) as the hydrosilane at 100 °C.
创建时间：
2016-02-13
