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Self-Assembly of Nanometer-Sized Boroxine Cages from Diboronic Acids

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Figshare2016-02-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Self_Assembly_of_Nanometer_Sized_Boroxine_Cages_from_Diboronic_Acids/2205481
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By use of the reversible trimerization of boronic acids, the series of boroxine cages 3-mer, 6-mer, and 12-mer were constructed from rationally designed diboronic acids whose bond angles between two C–B bonds are 60°, 84°, and 117°, respectively. Boroxine cages 6-mer and 12-mer have 1.5 and 2.5 nm sized cavities, respectively.
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2016-02-15
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