Formation of Novel T‑Shaped NNN Ligands via Rare-Earth Metal-Mediated Si–H Activation
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https://figshare.com/articles/dataset/Formation_of_Novel_T_Shaped_NNN_Ligands_via_Rare_Earth_Metal_Mediated_Si_H_Activation/2327812
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Reactions of silylamides [Ln{N(SiHMe2)2}3(thf)2] with sterically crowded terphenylamine DmpNH2 (Dmp = 2,6-Mes2C6H3 with Mes = 2,4,6-Me3C6H2) afforded via a template reaction the formation of a new tridentate ligand, and derived complexes of composition [LnN{SiMe2N(Dmp)}2] (Ln = Ce, Pr) were obtained. Usage of the even more bulky amine Ar*NH2 (Ar* = 2,6-Trip2C6H3 with Trip = 2,4,6-iPr3C6H2) yielded the free protonated ligand NH{SiMe2NH(Ar*)}2.
创建时间：
2016-02-18
