An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum
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https://figshare.com/articles/dataset/An_Unexpected_Mechanism_of_Hydrosilylation_by_a_Silyl_Hydride_Complex_of_Molybdenum/2560390
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资源简介：
Carbonyl hydrosilylation catalyzed by (ArN)Mo(H)(SiH2Ph)(PMe3)3 (3) is unusual
in that
it does not involve the expected Si–O elimination from intermediate
(ArN)Mo(SiH2Ph)(OiPr)(PMe3)2 (7). Instead, 7 reversibly
transfers β-CH hydrogen from the alkoxide ligand to metal.
创建时间：
2012-01-16
