Synthesis of Cu(II)-Organophosphonate Framework with Predefined Void Spaces
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https://figshare.com/articles/dataset/Synthesis_of_Cu_II_Organophosphonate_Framework_with_Predefined_Void_Spaces/2104009
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资源简介：
Here we report the first utilization
of the novel methane tetra-p-phenylphosphonic acid
(MTPPA) ligand for the preparation of metal complexes with Cu(II).
The hydrothermal and solvothermal reactions of tetratopic MTPPA as
a bridging ligand in conjunction with the square pyramidal {Cu(terpy)}2+ and {Cu2(pbterpy)}4+, (where terpy
= 2,2′:6′,2″-Terpyridine and pbterpy = 4′,4″″-(1,4-Phenylene)bis(2,2′:6′,2″-terpyridine))
as prefixed corner building units have produced one-dimensional [{Cu(terpy)}2(MTPPA-H5) (MTPPA-H6)]·(4.25H2O)(H3O) (1) and two-dimensional [{Cu2(pbterpy)}MTPPA-H4] (2), respectively. The structures
were characterized by single crystal X-ray diffraction and TGA.
创建时间：
2016-02-12
