Selective Lithiation, Magnesiation, and Zincation of Unsymmetrical Azobenzenes Using Continuous Flow
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https://figshare.com/articles/dataset/Selective_Lithiation_Magnesiation_and_Zincation_of_Unsymmetrical_Azobenzenes_Using_Continuous_Flow/4754413
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资源简介：
A mild and general set of metalation
procedures for the functionalization
of unsymmetrical azobenzenes using a commercially available continuous-flow
setup is reported. The metalations proceed with TMPLi under convenient
conditions (0 °C, 20 s), and various classes of electrophiles
can be used. With sensitive substrates, an in situ trapping metalation
in which TMPLi is added to a mixture of the azobenzene and ZnCl2 or MgCl2·LiCl was very effective for achieving
high yields.
创建时间：
2017-03-15
