Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands
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https://figshare.com/articles/dataset/Monomeric_Platinum_II_Hydroxides_Supported_by_Sterically_Dominant_Diimine_Ligands/2524975
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资源简介：
The use of two new highly sterically bulky α-diimine
ligands
for the stabilization of neutral, monomeric platinum(II) hydroxo complexes
is described. Halide abstraction from LPtCl2 complexes
of these ligands in the presence of water, followed by deprotonation
of the cationic aquo complex, leads to LPt(OH)Cl and LPt(OH)2. The latter can be reprotonated with HNTf2 to yield a
highly fluxional hydroxoaquoplatinum(II) cation.
创建时间：
2016-02-20
