Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts
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https://figshare.com/articles/dataset/Visible_Light_Mediated_Utilization_of_Aminoalkyl_Radicals_Addition_to_Electron_Deficient_Alkenes_Using_Photoredox_Catalysts/2547781
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资源简介:
Synthetic use of α-aminoalkyl radicals formed by single electron oxidation of amines is quite limited. Here we demonstrate addition of α-aminoalkyl radicals to electron-deficient alkenes by visible-light-mediated electron transfer using transition metal polypyridyl complexes as photocatalysts, via a sequential redox pathway.
创建时间:
2016-02-22



