Catalyst Control in Sequential Asymmetric Allylic Substitution: Stereodivergent Access to N,N-Diprotected Unnatural Amino Acids
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https://figshare.com/articles/dataset/Catalyst_Control_in_Sequential_Asymmetric_Allylic_Substitution_Stereodivergent_Access_to_i_N_N_i_Diprotected_Unnatural_Amino_Acids/2635282
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The sequential use of Cu-catalyzed asymmetric allylic alkylation, olefin cross-metathesis, and Ir-catalyzed asymmetric allylic amination allows the concise, stereodivergent synthesis of complex chiral amines with complete regiocontrol and good diastereoselectivity, exemplified by the synthesis of a pair of diastereoisomeric unnatural branched amino acid derivatives.
创建时间：
2016-02-23
