Synthesis and Structural Characterization of Homoleptic 1,2,4-Diazaphospholide Alkaline Earth Metal Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_Homoleptic_1_2_4_Diazaphospholide_Alkaline_Earth_Metal_Complexes/2237086
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资源简介：
The alkaline earth metal complexes
[(η2-3,5-tBu2dp)(μ-Mg)(η1:η1-3,5-tBu2dp)]2 (2), {[(η2-3,5-tBu2dp)(μ-η2:η5-3,5-tBu2dp)(μ-η2:η1-3,5-tBu2dp)Ca]2(μ-Ca)} (3), [Sr(3,5-tBu2dp)2]m (4), [Ba(3,5-tBu2dp)2)]n (5), and [η1-{H(3,5-tBu2dp)}2Ca(η2-3,5-tBu2dp)2] (6), bearing bulky 1,2,4-diazaphospholide ligands [3,5-tBu2dp]− ([3,5-tBu2dp]− = 3,5-di-tert-butyl-1,2,4-diazaphospholide), were prepared. The structures of
magnesium and calcium 1,2,4-diazaphospholide complexes represent homoleptic
1,2,4-diazaphospholide alkaline earth metal oligomers with a novel
array of metal–ligand binding modes.
创建时间：
2014-11-10
