Annulation of Benzamides with [60]Fullerene through Palladium(II)-Catalyzed C−H Bond Activation
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https://figshare.com/articles/dataset/Annulation_of_Benzamides_with_60_Fullerene_through_Palladium_II_Catalyzed_C_H_Bond_Activation/2681284
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Palladium-catalyzed heteroannulation of N-substituted benzamides with [60]fullerene, which proceeds through direct sp2 C−H bond activation to form 7-membered ring pallada-intermediate with C60, led to formation of [60]fulleroisoquinolinones in moderate to good yields (8−64% based on recovered C60). A plausible reaction pathway is proposed.
创建时间:
2016-02-23



