Synthesis and Structure of (OC)<sub>5</sub>W(η<sup>1</sup>-GaH<sub>3</sub>·(quinuclidine)): The First Gallane-Coordinated Transition-Metal Complex
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The first gallane-coordinated metal complex, (OC)5W(η1-GaH3·(quinuclidine)) (2), was synthesized by photolysis of a ca. 1:1 mixture of W(CO)6 and quinuclidine-coordinated gallane, H3Ga·(quinuclidine) (1), in toluene and by the reaction of (OC)5W(THF) with 1 equiv of gallane 1 in THF. X-ray crystal structure analysis of 2 revealed that gallane 1 is bound to the tungsten fragment via a W−H−Ga three-center−two-electron bond.
创建时间：
2016-08-26
