An Unprecedented Fe36 Phosphonate Cage
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/An_Unprecedented_Fe_sub_36_sub_Phosphonate_Cage/2442343
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The reaction of 2-pyridylphosphonic acid (LH2) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe36L44(H2O)48}]20+ (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1a revealed antiferromagnetic coupling between the spins on adjacent FeIII ions.
创建时间:
2016-02-19



