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Diastereoselective Pd-Catalyzed Anomeric C(sp<sup>3</sup>)–H Activation: Synthesis of α‑(Hetero)aryl C‑Glycosides

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NIAID Data Ecosystem2026-03-12 收录
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Anomeric C–H bond activation is an unsolved long-standing synthetic challenge. Herein, we report a diastereoselective Pd-catalyzed anomeric C­(sp3)–H activation methodology that allows the synthesis of elusive C-(hetero)­aryl glycosides with an exclusive α-selectivity.

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2021-01-25
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