DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2‑Perfluoroalkynoate
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https://figshare.com/articles/dataset/DABCO_Catalyzed_Synthesis_of_Trifluoromethylated_Furans_from_Propargyl_Alcohols_and_Methyl_2_Perfluoroalkynoate/2316793
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资源简介：
The
DABCO-catalyzed reaction of propargyl alcohols with methyl
2-perfluoroalkynoate to give trifluoromethylated furans in up to 98%
yield under mild conditions has been developed. The established allene–enol
and control experiments indicate that the reaction should proceed
through a Michael addition and Claisen rearrangement/cyclization process.
创建时间：
2016-02-18
