Cationic Copper(I) Carbene Complexes: Synthesis and Structures of a Tricoordinate Copper(I) Carbene Water Complex and a Dicoordinate Carbene Complex
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https://figshare.com/articles/dataset/Cationic_Copper_I_Carbene_Complexes_Synthesis_and_Structures_of_a_Tricoordinate_Copper_I_Carbene_Water_Complex_and_a_Dicoordinate_Carbene_Complex/2466553
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资源简介：
A series of tricoordinate cationic copper(I) carbene
complexes
of the type [Cu{CR1(OR2)}(MeCN)(L)][PF6] (R1 = (E)-CHCH-2-furyl,
R2 = (1R,2S,5R)-menthyl), L = MeCN, THF, SMe2, H2O) were prepared from the carbene complex [Cu{=CR1(OR2)}(MeCN)(Et2O)][PF6] through a ligand-exchange
reaction with the appropriate ligand (L). The synthesis of the cationic
dicoordinate copper(I) carbene complex [Cu{CR1(OR2)}(MeCN)][PF6] is also reported. The solid-state
structures of the tricoordinate complex bearing water as ligand and
of the dicoordinate complex are discussed.
创建时间：
2016-02-20
