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One-Pot Synthesis of Polysubstituted Spirofluorene–Indene via Ru(II)-Catalyzed [3 + 2] Annulation and Intramolecular Friedel–Crafts Cyclization

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https://figshare.com/articles/dataset/One_Pot_Synthesis_of_Polysubstituted_Spirofluorene_Indene_via_Ru_II_Catalyzed_3_2_Annulation_and_Intramolecular_Friedel_Crafts_Cyclization/2120713
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Ru­(II)-catalyzed one-pot synthesis of polysubstituted spirofluorene–indenes via [3 + 2] annulation and then intramolecular Friedel–Crafts alkylation has been achieved. The simple method provides a broad scope of aryl ketones and internal alkynes, achieving PAHs skeletons in moderate to good yields.
创建时间:
2016-02-12
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