Synthesis of a Rhodium Carbonyl Phosphaalkenyl–Phosphido Complex: A Phosphorus Congener of Schiff Base Type N,N′-Chelating Monoanionic Ligands
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https://figshare.com/articles/dataset/Synthesis_of_a_Rhodium_Carbonyl_Phosphaalkenyl_Phosphido_Complex_A_Phosphorus_Congener_of_Schiff_Base_Type_N_N_Chelating_Monoanionic_Ligands/2312656
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资源简介：
A monoanionic, bidentate phosphaalkenyl–phosphido
ligand
was designed, synthesized, and used for the complexation of a rhodium
carbonyl fragment. The characterization of the latter revealed delocalized
π electrons on the phosphaalkenyl–phosphide moiety. The
catalytic activity of this rhodium carbonyl complex has been demonstrated
in a hydrosilylation reaction.
创建时间：
2014-03-24
