Aminocatalytic Asymmetric exo-Diels–Alder Reaction with Methiodide Salts of Mannich Bases and 2,4-Dienals to Construct Chiral Spirocycles
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Aminocatalytic_Asymmetric_i_exo_i_Diels_Alder_Reaction_with_Methiodide_Salts_of_Mannich_Bases_and_2_4_Dienals_to_Construct_Chiral_Spirocycles/2443183
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资源简介：
An asymmetric exo-Diels–Alder reaction of α-methylene carbonyl compounds, generated in situ from stable methiodide salts of Mannich bases, with 2,4-dienals, has been developed through trienamine activation of a chiral secondary amine. A spectrum of spirocyclanes with high molecular complexity was efficiently constructed in moderate to excellent diastereo- and enantioselectivity.
创建时间：
2016-02-19
