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Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine Boron Triflate

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Synthesis_Characterization_and_Reactivity_Studies_of_Subphthalocyanine_Boron_Triflate/4532528
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The highly reactive subphthalocyanine boron triflate complex ((subPc)­BOTf) was isolated and characterized by X-ray diffraction and spectroscopic methods. The combination of (subPc)­BOTf and bis­(trimethyl­silyl)­amide (LiHMDS) yielded a “kinetically induced” frustrated Lewis pair system capable of activating a variety of substrates such as ethers, amides, and ketones. These reactions demonstrate the high reactivity of (subPc)­BOTf toward organic molecules.
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2017-01-09
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