Enantioselective γ‑Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement
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https://figshare.com/articles/dataset/Enantioselective_Alkylation_of_Unsaturated_Malonates_and_Ketoesters_by_a_Sequential_Ir_Catalyzed_Asymmetric_Allylic_Alkylation_Cope_Rearrangement/3180682
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资源简介：
A catalytic, enantioselective
γ-alkylation of α,β-unsaturated malonates and ketoesters
is reported. This strategy entails a highly regio- and enantioselective
iridium-catalyzed α-alkylation of an extended enolate, and a
subsequent translocation of chirality to the γ-position via
a Cope rearrangement.
创建时间：
2016-04-21
