Enantioselective Desymmetrization via Carbonyl-Directed Catalytic Asymmetric Hydroboration and Suzuki–Miyaura Cross-Coupling
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https://figshare.com/articles/dataset/Enantioselective_Desymmetrization_via_Carbonyl_Directed_Catalytic_Asymmetric_Hydroboration_and_Suzuki_Miyaura_Cross_Coupling/2194228
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The rhodium-catalyzed enantioselective desymmetrization of symmetric γ,δ-unsaturated amides via carbonyl-directed catalytic asymmetric hydroboration (directed CAHB) affords chiral secondary organoboronates with up to 98% ee. The chiral γ-borylated products undergo palladium-catalyzed Suzuki–Miyaura cross-coupling via the trifluoroborate salt with stereoretention.
创建时间：
2016-02-14
