Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cyclization of 1,6-Enynes with Aliphatic and Aromatic Alkenes
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https://figshare.com/articles/dataset/Rhodium-Catalyzed_Asymmetric_2_2_2_Cyclization_of_1_6-Enynes_with_Aliphatic_and_Aromatic_Alkenes/5028638
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资源简介：
It has been established that a cationic
rhodium(I)/(R)-MeO-BIPHEP complex catalyzes the asymmetric
[2 + 2 + 2] cyclization
of 1,6-enynes with aliphatic and aromatic alkenes to produce chiral
cyclic dienes through β-hydride elimination from rhodacycle
intermediates. Thus, obtained chiral cyclic dienes could be converted
to chiral spirocompounds without racemization.
创建时间：
2017-05-22
