Organometallic Ionic Liquids from Cationic Arene–Ruthenium Complexes
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https://figshare.com/articles/dataset/Organometallic_Ionic_Liquids_from_Cationic_Arene_Ruthenium_Complexes/2445421
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资源简介：
Ionic liquids comprised of cationic arene–ruthenium
chelate
complexes and the bis(trifluoromethanesulfonyl)amide anion (=Tf2N), [(arene)RuCl(L)](Tf2N), where L = MeS(CH2)nSR (R = Me, Bu; n = 1–3), Me2N(CH2)2NMe2 and arene = p-cymene, C6H6, have been prepared, and their thermal properties, structures,
and reactivities have been investigated. These liquids undergo direct
ligand exchange reactions in line with their thermal stabilities.
Thermogravimetric analysis revealed that the thermal stabilities of
the complexes are higher as the bridging group of the chelate ligand
becomes longer. The complexes with MeSCH2SMe transform
thermally into dinuclear complexes. The coordination structures were
determined crystallographically.
创建时间：
2013-02-11
