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Ruthenium-Catalyzed Oxypropargylation of Alkenes

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https://figshare.com/articles/dataset/Ruthenium_Catalyzed_Oxypropargylation_of_Alkenes/2886904
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The ruthenium-catalyzed oxypropargylation of alkenes with propargylic alcohols and simple alcohols has been found via ruthenium−allenylidene complexes as key intermediates. As a synthetic application, an intramolecular cyclization using this method has been developed to give the corresponding anti-1-alkoxy-3-ethynylindanes in high to excellent yields with a high diastereoselectivity.
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2009-01-12
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