Synthesis of Diruthenium Complexes Containing Chiral Thiolate-Bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone
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https://figshare.com/articles/dataset/Synthesis_of_Diruthenium_Complexes_Containing_Chiral_Thiolate-Bridged_Ligands_and_Their_Application_to_Catalytic_Propargylic_Alkylation_of_Propargylic_Alcohols_with_Acetone/3774393
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资源简介:
Novel diruthenium complexes containing
chiral thiolate-bridged ligands are synthesized and
characterized crystallographically. The chiral diruthenium complexes promote enantioselective propargylic
alkylation of propargylic alcohols with acetone to give
the corresponding propargylic alkylated products in good
yields with moderate enantioselectivities (up to 35% ee).
创建时间:
2016-08-26



