Tribenzylamine C–H Activation and Intermolecular Hydrogen Transfer Promoted by WCl6
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https://figshare.com/articles/dataset/Tribenzylamine_C_H_Activation_and_Intermolecular_Hydrogen_Transfer_Promoted_by_WCl_sub_6_sub_/2308573
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The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the iminium salt [(PhCH2)2NCHPh][WCl6], 1, and the ammonium one [tbaH][WCl6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects.
创建时间：
2016-02-17
