Synthesis and Characterization of Silyl-Bridged Dinuclear Cobalt Complexes Supported by an N‑Heterocyclic Carbene
收藏Figshare2019-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Silyl-Bridged_Dinuclear_Cobalt_Complexes_Supported_by_an_N_Heterocyclic_Carbene/7709855
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A cobalt dialkyl with an N-heterocyclic carbene [Co(CH2SiMe3)2(IPr)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene) underwent successive Si–H bond cleavage of hydrosilanes. The reaction paths were highly dependent on the bulkiness of the hydrosilanes, which led to the formation of various μ-silyl-bridged dicobalt complexes, [{Co(IPr)}2(μ-SiH2Hex)4], [{Co(IPr)}2(μ-SiH2Ph)3(H)3], and [{Co(IPr)}2(μ-SiHPh2)(μ-H)2].
创建时间：
2019-02-12
