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Ni-Catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2

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Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ni_Catalyzed_Divergent_Cyclization_Carboxylation_of_Unactivated_Primary_and_Secondary_Alkyl_Halides_with_CO_sub_2_sub_/2163898
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A user-friendly Ni-catalyzed reductive cyclization/carboxylation of unactivated alkyl halides with CO2 is described. The protocol operates under mild conditions with an excellent chemoselectivity profile and a divergent syn/anti selectivity pattern that can be easily modulated by the substrate utilized.
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2016-02-13
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