Three-Component Reaction of Aryl Diazoacetates, Alcohols, and Aldehydes (or Imines): Evidence of Alcoholic Oxonium Ylide Intermediates
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The Rh(II)-catalyzed three-component reaction of aryl diazoacetates, alcohols and aldehydes was explored, which provided evidence of alcoholic oxonium ylide formation for O−H insertion. A new C−C bond formation reaction where alcoholic oxonium ylides were trapped by electron-deficient aryl aldehydes (or imines) was realized.
创建时间:
2005-01-06



