Reversible Dehydration Behavior Reveals Coordinatively Unsaturated Metal Sites in Microporous Aluminum Phosphonates
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Reversible_Dehydration_Behavior_Reveals_Coordinatively_Unsaturated_Metal_Sites_in_Microporous_Aluminum_Phosphonates/2250445
下载链接
链接失效反馈官方服务：
资源简介：
Incorporation of the same ligand
into three different aluminum
phenylenediphosphonates (Al(H2O)(O3PC6H4PO3H) (1), Al4(H2O)2(O3PC6H4PO3)3 (2), and Al4(H2O)4(O3PC6H4PO3)2.84(OH)0.64 (3)) was accomplished by varying the synthetic conditions.
The compounds have different sorption properties; however, all exhibit
reversible dehydration behavior. The structures of the hydrated and
dehydrated phases were determined from powder X-ray diffraction data.
Compounds 2 and 3 were found to be microporous,
while compound 1 was found to be nonporous. The stability
of the dehydrated phase and the resulting porosity was found to be
influenced by the change in the structure upon loss of water.
创建时间：
2016-02-16
