Highly Enantioselective Organocatalytic Oxidative Kinetic Resolution of Secondary Alcohols Using Chirally Modified AZADOs
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https://figshare.com/articles/dataset/Highly_Enantioselective_Organocatalytic_Oxidative_Kinetic_Resolution_of_Secondary_Alcohols_Using_Chirally_Modified_AZADOs/2863717
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资源简介:
A highly enantioselective organocatalytic oxidative kinetic resolution (OKR) of racemic secondary alcohols has been accomplished using asymmetric organocatalysis. A panel of chirally modified 2-azaadamantane N-oxyls (AZADOs) exhibit superior catalytic activity and high enantioselectivity, allowing us to obtain optically active secondary alcohols with a krel value up to 82.2.
创建时间:
2009-04-16



