Rh-Catalyzed Reactions of 3‑Diazoindolin-2-imines: Synthesis of Pyridoindoles and Tetrahydrofuropyrroloindoles
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https://figshare.com/articles/dataset/Rh_Catalyzed_Reactions_of_3_Diazo_indolin_2_imines_Synthesis_of_Pyrido_indoles_and_Tetra_hydro_furopyrrolo_indoles/2130271
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资源简介:
The rhodium-catalyzed
reactions of 3-diazoindolin-2-imines with
furans and dihydrofuran furnished 9H-pyrido[2,3-b]indoles and tetrahydrofuro[3′,2′:4,5]pyrrolo[2,3-b]indoles, respectively. A cascade reaction mechanism
involving an α-imino rhodium carbene intermediate is proposed.
The starting materials are readily available, and the procedure is
facile and efficient.
创建时间:
2016-02-13



