Synthesis of Complex Hexacyclic Compounds via a Tandem Rh(II)-Catalyzed Double-Cyclopropanation/Cope Rearrangement/Diels–Alder Reaction
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Complex_Hexacyclic_Compounds_via_a_Tandem_Rh_II_Catalyzed_Double_Cyclopropanation_Cope_Rearrangement_Diels_Alder_Reaction/2040543
下载链接
链接失效反馈官方服务：
资源简介：
Treatment
of (E)-1-(methoxymethylene)-1,2,3,4-tetrahydronaphthalene
with styryl diazoacetates in the presence of catalytic amounts of
the dirhodium complex Rh2(S-DOSP)4 provides a highly enantioenriched hexacyclic product with
10 new stereogenic centers. The transformation proceeds by a cascade
sequence starting with a double cyclopropanation of a benzene ring,
followed by a Cope rearrangement of a divinylcyclopropane and then
an intramolecular Diels–Alder cycloaddition.
创建时间：
2015-12-17
